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4-(Bromo-methyl)-benz-yltriphenyl-phospho-nium bromide acetonitrile monosolvate

Burke, Benjamin P ; Greenman, Peter ; Smith, Adam M ; Archibald, Stephen J

Acta crystallographica. Section E, Structure reports online, 01 November 2012, Vol.68(Pt 11), pp.o3202 [Rivista Peer Reviewed]

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  • Titolo:
    4-(Bromo-methyl)-benz-yltriphenyl-phospho-nium bromide acetonitrile monosolvate
  • Autore: Burke, Benjamin P ; Greenman, Peter ; Smith, Adam M ; Archibald, Stephen J
  • Note di contenuto: In the title compound, C(26)H(23)BrP(+)·Br(-)·C(2)H(3)N, the dihedral angles between the plane of the benzylic phenyl ring attached to the P atom and the planes of the three directly attached phenyl rings are 34.04 (12), 45.48 (13) and 87.18 (9)°. In the crystal, centrosymmetric pairs of cations and anions are linked into dimeric aggregates via C-H⋯Br hydrogen bonds. There is also a C-H⋯N hydrogen bond to the acetonitrile solvent mol-ecule.
  • Fa parte di: Acta crystallographica. Section E, Structure reports online, 01 November 2012, Vol.68(Pt 11), pp.o3202
  • Soggetti: Engineering ; Chemistry
  • Lingua: Inglese
  • Tipo: Articolo
  • Identificativo: ISSN: 1600-5368 ; PMID: 23284511 Version:1 ; DOI: 10.1107/S1600536812042341
  • Fonte: MEDLINE/PubMed (U.S. National Library of Medicine)

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