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The reactions of dichloro-bis(μ-chloro)-bis(η 6- p-cymene)diosmium(II) and -diruthenium(II) with hexamethyldialuminium

Cabeza, Javier A ; Taylor, Brian F ; Maitlis, Peter M

Inorganica Chimica Acta, 1987, Vol.133(1), pp.67-70 [Rivista Peer Reviewed]

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  • Titolo:
    The reactions of dichloro-bis(μ-chloro)-bis(η 6- p-cymene)diosmium(II) and -diruthenium(II) with hexamethyldialuminium
  • Autore: Cabeza, Javier A ; Taylor, Brian F ; Maitlis, Peter M
  • Note di contenuto: The reactions of [( p -MeC 6 H 4 CHMe 2 ) 2 M 2 Cl 4 ] (M= Os, Ru) with Al 2 Me 6 in toluene give solutions which contain Al 2 Me 4 Cl 2 and heterometallic species formulated as [{( p -MeC 6 H 4 CHMe 2 )MMe 2 } 2 (Al 2 Me 6 )] ( 4 ) on the basis of low-temperature 13 C{ 1 H} NMR spectroscopy at 62.9 MHz. Reaction of 4 with PPh 3 gives [( p -MeC 6 H 4 CHMe 2 )MMe 2 (PPh 3 )].
  • Fa parte di: Inorganica Chimica Acta, 1987, Vol.133(1), pp.67-70
  • Soggetti: Chemistry
  • Lingua: Inglese
  • Tipo: Articolo
  • Identificativo: ISSN: 0020-1693 ; E-ISSN: 1873-3255 ; DOI: 10.1016/S0020-1693(00)84374-1

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