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The preparation of [(η-C 5H 5)RuCl(PPh 3) 2] from [RuHCl(PPh 3) 3] and penta-1,4-diene; carboncarbon bond formation by dehydrogenation

Mann, Brian E ; Manning, Paul W ; Spencer, Catriona M

Journal of Organometallic Chemistry, 1986, Vol.312(3), pp.C64-C66 [Rivista Peer Reviewed]

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  • Titolo:
    The preparation of [(η-C 5H 5)RuCl(PPh 3) 2] from [RuHCl(PPh 3) 3] and penta-1,4-diene; carboncarbon bond formation by dehydrogenation
  • Autore: Mann, Brian E ; Manning, Paul W ; Spencer, Catriona M
  • Note di contenuto: [RuHCl(PPh 3) 3] reacts with penta-1,4-diene in CD 2Cl 2, to give initially [(η 3-C 5H 9)RuCl(PPh 3) 2]. Dehydrogenation by an excess of pentadiene produces [(η 5-C 5H 7)RuCl(PPh 3) 2]. When acetone is used as the dehydrogenating agent, then the reaction proceeds further to yield [(η-C 5H 5)RuCl(PPh 3) 2]. This known compound was prepared quantitatively by refluxing [RuHCl(PPh 3) 3] and penta-1,4-diene in methyl ethyl ketone.
  • Fa parte di: Journal of Organometallic Chemistry, 1986, Vol.312(3), pp.C64-C66
  • Soggetti: Chemistry
  • Lingua: Inglese
  • Tipo: Articolo
  • Identificativo: ISSN: 0022-328X ; E-ISSN: 1872-8561 ; DOI: 10.1016/0022-328X(86)80332-1
  • Fonte: ScienceDirect Journals (Elsevier)

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